From there, it gets more technical, but experts say the key is controlling the pressure.
"Penalty shootouts are really a psychological game," said Geir Jordet, associate professor at the Norwegian School of Sport Science in Oslo who has studied shootouts extensively.
"It's not so much about technique or skill, it's about players choking. Shootouts are not decided by great shots or spectacular penalties. They are decided by the one, two or three players who fail because the pressure gets to them."
Jordet's research has highlighted several reasons why some players and countries fail.
English, Spanish, Italian and Dutch players, for example, rank high in terms of "star" status, having enjoyed club success and great popularity at home, which piles on more pressure.
His research has shown English players take kicks quicker than players from any other country, reflecting their desire to get them over as soon as possible.
England's Frank Lampard reacts after missing penalty during penalty shootout in World Cup 2006 quarter-final soccer match
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