With the Germans, who lost the Euro 2008 final to the Spaniards by the same score, boxed into their own half, Spain kept up the pressure, with Puyol heading an Andres Iniesta cross from the right narrowly over the bar after 15 minutes.
Germany's Piotr Trochowski, who replaced the suspended Thomas Mueller on the right, stretched Spain goalkeeper Iker Casillas with a well-struck low drive.
Pedro and Sergio Ramos continued to single out Germany left back Jerome Boateng as a weakness, cutting the ball back from the wing for midfielder Xabi Alonso who twice fired wide early in the second half.
The Spaniards came agonisingly close in the 58th minute with a Pedro shot that forced a spectacular save from Neuer before Iniesta cut the ball across the face of goal a metre ahead of the sliding Villa.
Germany remained on the backfoot and 17 minutes from time were punished when Puyol headed the winner leaving Spain to soak up some late pressure before reaching the final.
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